DTBP-二叔丁基過氧化物--CAS.110-05-4
公司: | 山東海京新材料有限公司 |
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聯(lián)系人: | 劉總 |
手機(jī): | 13220762561 |
電話: | 0536-8688945 |
地址: | 山東省濰坊市濱海區(qū)大家洼街道?;著S 都大廈1號樓601 |
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產(chǎn)品介紹
商品名稱: DTBP
中文名稱:二叔丁基過氧化物
化學(xué)名稱:二叔丁基過氧化物
分子式:C8H17O2
分子量:146.2
理論活性氧量:10.94%
CAS號:110-05-4
UN No. 3107
Einecs:203-733-6
IMO/IMDG 5227
級別: 5.2
公路運(yùn)輸(ARD):5.2
E型液體有機(jī)過氧化物。
性質(zhì):本品為微黃色透明液體,可用客戶指定的溶劑稀釋。不溶于水,溶于多數(shù)有機(jī)溶劑,閃點:12.5℃ (閉皿),18℃(開皿),沸點:109℃,凝固點:-40℃。粘度(20℃):0.9mPa.s 。
主要分解產(chǎn)物:叔丁醇、異丙烯、甲烷、乙烷等。
指標(biāo):
半衰期:
0.1小時:164℃
1小時:141℃
10小時:121℃
熱穩(wěn)定性數(shù)據(jù):
自加速分解溫度(SADT):80℃
危急溫度(Tem):75℃
貯存溫度(Tsmax):-30/40 ℃
活化能E(KJ/mol):130.74
技術(shù)標(biāo)準(zhǔn):
外觀: 淡黃色透明液體
含量 :99% min
TBHP:最大0.1%
比重(25 ℃):0.793-0.803
折光:1.385-1.391
用途:
1.用作乙烯基、雙烯基單體的聚合引發(fā)劑,推薦的交聯(lián)溫度范圍為180-240 ℃。在菅式法和釜式法高壓聚乙烯聚合工藝中,它是一種常用的引發(fā)劑,交聯(lián)的溫度范圍為240-280 ℃。
2、為不飽和聚酯的高溫固化劑。
3、是二烯類橡膠的有硫化劑,適合于厚橡膠制品硫化。拉伸強(qiáng)度,伸長率和耐壓縮和變形性能好,獲FDA批準(zhǔn),適合于絕大多數(shù)橡膠、聚氨酯彈性體、硅橡膠的硫化,可獲得白色和各種鮮艷色彩的橡膠制品。
4、用于聚丙烯高速紡絲(丙綸)工業(yè)中,做分子量調(diào)節(jié)劑(用于降溫母粒生產(chǎn)中)。具有分子量分布窄,熔體指數(shù)高,紡絲均勻的特點,是聚丙烯修飾中使用的優(yōu)良降解劑,在聚丙烯中加入該品,可制成控制流變聚丙烯,提高流動性,使聚丙烯快速模壓成為可能,同時可減少模壓產(chǎn)生的形變。經(jīng)過改性的聚丙烯可制成薄膜料。
5、用于油品添加劑和變壓器油的降凝劑。
包裝及運(yùn)輸:
我廠的標(biāo)準(zhǔn)包裝為20公斤的聚乙烯包裝。也可根據(jù)客戶的要求的包裝尺寸供貨,客戶可在訂貨時提出要求。
儲存注意事項:
1.儲存于陰涼通風(fēng)的空間內(nèi),倉溫不超過30℃。
2.遠(yuǎn)離火種,熱源。與酸類,還原劑,易燃物,可燃物,還原劑等分開存放。
3.儲存間的照明通風(fēng)等設(shè)施采用防爆型,開關(guān)設(shè)在戶外。
4.搬運(yùn)時應(yīng)小心輕放,防止包裝及容器的破損,禁止撞擊和振蕩,分裝和搬運(yùn)作業(yè)要注意個人防護(hù)。
5.請客戶在貯運(yùn)和使用本產(chǎn)品時仔細(xì)閱讀本我廠《技術(shù)說明書(MSDS) 》。
產(chǎn)品有效期:
在嚴(yán)格按照生產(chǎn)廠家提示的條件貯存、運(yùn)輸。三個月內(nèi)產(chǎn)品質(zhì)量可確實保證。
火災(zāi)防護(hù):
1、本產(chǎn)品可能因受熱而劇烈分解,會猛烈起火,少量產(chǎn)品小火應(yīng)迅速用泡沫或干粉滅火器進(jìn)行滅火。
2、大火應(yīng)迅速撤達(dá)到不危險的距離以外并用水槍樸救,通知消防部門處理。
Product Name: DTBP
English name: Di-tert-butyl peroxide
Chemical name: di-tert-butyl peroxide
Molecular formula:C8H17O2
Molecular weight:146.2
Theoretical active oxygen content:10.94%
CAS.:110-05-4
UN No. 3107
Einecs:203-733-6
IMO/IMDG 5227
Level: 5.2
ARD:5.2
E-type liquid organic peroxide.
Property: This product is a slightly yellow transparent liquid, which can be diluted with the solvent specified by the customer. Insoluble in water, soluble in most organic solvents, flash point: 12.5 ℃ (closed dish), 18 ℃ (open dish), boiling point: 109 ℃, freezing point: -40 ℃. Viscosity (20 ℃): 0.9mPa. s.
Main decomposition products: tert butanol, isopropanol, methane, ethane, etc.
Safety indicators:
Half life:
0.1 hour: 164 ℃
1 hour: 141 ℃
10 hours: 121 ℃
Thermal stability data:
Self accelerating decomposition temperature (SADT): 80 ℃
Emergency temperature (Tem): 75 ℃
Storage temperature (Tsmax): -30/40 ℃
Activation energy E (KJ/mol): 130.74
Technical standards:
Appearance: Light yellow transparent liquid
Content:99% min
TBHP:0.1%max
Specific gravity(25 ℃):0.793-0.803
Refraction:1.385-1.391
Purpose:
1. As a polymerization initiator for vinyl and dienyl monomers, the recommended crosslinking temperature range is 180-240 ℃. It is a commonly used initiator in high-pressure polyethylene polymerization processes using the Kan method and the kettle method, with a crosslinking temperature range of 240-280 ℃.
2. It is a high-temperature curing agent for unsaturated polyester.
3. It is a vulcanizing agent for diene rubber, suitable for vulcanizing thick rubber products. Good tensile strength, elongation, compression and permanent deformation resistance, approved by FDA, suitable for vulcanization of the vast majority of rubber, polyurethane elastomers, and silicone rubber. It can obtain white and various bright colored rubber products.
4. Used in the high-speed spinning of polypropylene (polypropylene fiber) industry as a molecular weight regulator (used in the production of cooling masterbatch). It has the characteristics of narrow molecular weight distribution, high melt index, and uniform spinning, and is an excellent degradation agent used in polypropylene modification. By adding this product to polypropylene, it can be made into controlled rheological polypropylene, improve flowability, and make rapid molding of polypropylene possible, while reducing deformation caused by molding. Modified polypropylene can be made into thin film materials.
5. Used as oil additive and pour point depressant of transformer oil.
Packaging and transportation:
Our factory's standard packaging is 20 kilograms of polyethylene packaging. We can also supply according to the packaging size requested by the customer, and the customer can make requirements when placing an order.
Storage precautions:
1. Store in a cool and ventilated space, with a warehouse temperature not exceeding 30 ℃.
2. Keep away from sparks and heat sources. Store separately from acids, reducing agents, inflammables, combustibles, reducing agents, etc.
3. The lighting and ventilation facilities in the storage room are explosion-proof, with switches located outdoors.
4. When handling, care should be taken to prevent damage to packaging and containers, and impact and oscillation are prohibited. Personal protection should be taken during packaging and handling operations.
5. Please carefully read our factory's Safety Technical Manual (MSDS) when storing, transporting, and using this product.
Product validity period:
Store and transport in strict accordance with the manufacturer's instructions. The product quality can be guaranteed within three months.
Fire protection:
1. This product may decompose violently due to heating, and may ignite violently. A small amount of small fires should be put out quickly with foam or dry powder extinguishers.
2. The fire should be quickly evacuated to a safe distance and rescued with a water gun, and the fire department should be notified for handling.