TAPB-過氧化苯甲酸叔戊酯--CAS.4511-39-1
公司: | 山東海京新材料有限公司 |
---|---|
聯(lián)系人: | 劉總 |
手機(jī): | 13220762561 |
電話: | 0536-8688945 |
地址: | 山東省濰坊市濱海區(qū)大家洼街道海化街鳶 都大廈1號(hào)樓601 |
留言咨詢 更多信息 | |
分享: |
![]() |
產(chǎn)品介紹
商品名稱:TAPB
英文名稱:過氧化苯甲酸叔戊酯
化學(xué)名稱:過氧化苯甲酸特戊酯
分子式:C12H16O3
分子量:208.30
理論活性氧量:7.68%
性質(zhì):
本品為淡黃色透明液體,沸點(diǎn)124℃ (760mmHg),分解溫度76-77℃??捎每蛻糁付ǖ娜軇┫♂尅2蝗苡谒?,溶于多數(shù)有機(jī)溶劑,比重(25℃) 1.036-1.045, 折光(25℃)1.495-1.500。
CAS號(hào):4511-39-1
UN No. 3103
C型液體有機(jī)過氧化物,二類危險(xiǎn)貨物包裝。
主要分解產(chǎn)物:叔丁醇、苯甲酸、甲烷、乙烷、苯等。
指標(biāo):
半衰期Half life:
0.1小時(shí):139℃ 0.1 hour: 139 ℃
1小時(shí):118℃ 1 hour: 118 ℃
10小時(shí):99℃ 10 hours: 99 ℃
熱穩(wěn)定性數(shù)據(jù):
自加速分解溫度(SADT):60℃
危急溫度(Tem):--
控制溫度(Tc):--
貯存溫度(Tsmax):--/20 ℃
活化能E(KJ/mol):147.2
技術(shù)標(biāo)準(zhǔn):
外觀:淡黃色透明液體
含量:98% min
有效氧:8.07% min
TBHP:1000mg/kg
無機(jī)及有機(jī)可水解氯化物:50mg/kg
用途:
1.高壓聚乙烯(LDPE)的優(yōu)良中溫引發(fā)劑,多用于管式或釜式法工藝, 可同引發(fā)劑PV(過氧化特戊酸叔丁酯),OT(過氧化-2-乙基已酸叔丁酯),引發(fā)劑TBPD(過氧化新癸酸叔丁酯)及二異丙苯過氧化氫等共同組成復(fù)合催化劑體系,聚合效果好。
2. 在苯乙烯懸浮聚合工藝中,引發(fā)劑C和過氧化苯甲酰(BPO)復(fù)配使用,是苯乙烯或苯乙烯共聚物常用的引發(fā)劑。
3.在丙烯酸酯類的聚合工藝中用引發(fā)劑C代替偶氮類引發(fā)劑,降低了樹脂中的毒性。它也可以用于醋酸乙烯酯的聚合反應(yīng)。
4. 是不飽和聚酯的高溫固化劑。該品廣泛地使用于玻璃鋼、涂料、膠粘劑等不飽和聚酯的固化過程中,如SMC、BMC、DMC的成型工藝中,本品是不飽和聚酯高溫固化選擇的固化劑,對(duì)模壓成型和拉擠成型都有理想的固化效果。如和BPO、TBPEH、CH等引發(fā)劑組成復(fù)配引發(fā)劑體系則效果更佳。
5. 是大部分橡膠的良好硫化劑(異丁烯類橡膠除外)。
6. 添加在油品中會(huì)大大提高其十六烷值。
包裝及運(yùn)輸:
標(biāo)準(zhǔn)包裝為25公斤的聚乙烯包裝。也可根據(jù)客戶的要求的包裝尺寸供貨,客戶可在訂貨時(shí)提出要求。
儲(chǔ)存注意事項(xiàng):
1.儲(chǔ)存于陰涼通風(fēng)的空間內(nèi),倉溫不超過30℃。
2. 遠(yuǎn)離火種,熱源。應(yīng)與酸類,還原劑,易燃物,可燃物,還原劑等分開存放。
3. 儲(chǔ)存間的照明通風(fēng)等設(shè)施采用防爆型,開關(guān)設(shè)在戶外。
4. 搬運(yùn)時(shí)應(yīng)小心輕放,防止包裝及容器的破損,禁止撞擊和振蕩,分裝和搬運(yùn)作業(yè)要注意個(gè)人防護(hù)。
5. 請(qǐng)客戶在貯運(yùn)和使用本產(chǎn)品時(shí)仔細(xì)閱讀本我廠《技術(shù)說明書(MSDS)》。
產(chǎn)品有效期:
在嚴(yán)格按照生產(chǎn)廠家提示的條件貯存、運(yùn)輸。六個(gè)月內(nèi)產(chǎn)品質(zhì)量可確實(shí)保證。
火災(zāi)防護(hù):
1. 本產(chǎn)品可能因受熱而劇烈分解,會(huì)猛烈起火,少量產(chǎn)品小火應(yīng)迅速用泡沫或干粉滅火器進(jìn)行滅火。
2. 大火應(yīng)迅速撤達(dá)到不危險(xiǎn)的距離以外并用水槍樸救,通知消防部門處理。
Product name:TAPB
English name:Tert-amyl peroxy benzoate
Chemical name: tert amyl peroxide benzoate
Molecular formula:C12H16O3
Molecular weight:208.30
Theoretical active oxygen content:7.68%
Property:
This product is a light yellow transparent liquid, with a boiling point of 124 ℃ (760mmHg) and a decomposition temperature of 76-77 ℃. Can be diluted with the solvent specified by the customer. Insoluble in water, soluble in most organic solvents, specific gravity (25 ℃) 1.036-1.045, refractive index (25 ℃) 1.495-1.500.
CAS.:4511-39-1
UN No. 3103
C-type liquid organic peroxide, packaging for Class II dangerous goods.
Main decomposition products: tert butanol, benzoic acid, methane, ethane, benzene, etc.
Safety indicators:
Half life:
0.1 hour: 139 ℃
1 hour: 118 ℃
10 hours: 99 ℃
Thermal stability data:
Self accelerating decomposition temperature (SADT): 60 ℃
Critical temperature (Tem):--
Control temperature (Tc):--
Storage temperature (Tsmax): --/20 ℃
Activation energy E (KJ/mol): 147.2
Technical standards:
Appearance: Light yellow transparent liquid
Content:98% min
Effective oxygen:8.07% min
TBHP:1000mg/kg
Inorganic and organic hydrolyzable chlorides: 50mg/kg
Purpose:
1. High pressure polyethylene (LDPE) is an excellent medium temperature initiator, commonly used in tubular or kettle processes. It can be combined with initiators PV (tert butyl peroxybutyrate), OT (tert butyl peroxy-2-ethylhexoate), TBPD (tert butyl peroxyneodecanoate), and diisopropylbenzene peroxide to form a composite catalyst system, resulting in better polymerization performance.
In the styrene suspension polymerization process, the combination of initiator C and benzoyl peroxide (BPO) is the most commonly used initiator for styrene or styrene copolymers.
3. In the polymerization process of acrylic esters, the use of initiator C instead of azo initiator reduces the toxicity in the resin. It can also be used for the polymerization reaction of vinyl acetate.
4. It is a high-temperature curing agent for unsaturated polyester. This product is widely used in the curing process of unsaturated polyester such as fiberglass, coatings, adhesives, etc., such as in the molding processes of SMC, BMC, DMC. It is the preferred curing agent for high-temperature curing of unsaturated polyester, and has very ideal curing effects for both compression molding and pultrusion molding. If a composite initiator system is composed of BPO, TBPEH, CH and other initiators, the effect is better.
5. It is a good vulcanizing agent for most rubbers (excluding isobutylene rubber).
6. It will greatly increase its cetane number when added to oil products.
Packaging and transportation:
The standard packaging is 25 kilograms of polyethylene packaging. We can also supply according to the packaging size requested by the customer, and the customer can make requirements when placing an order.
Storage precautions:
1. Store in a cool and ventilated space, with a warehouse temperature not exceeding 30 ℃.
2. Keep away from sparks and heat sources. It should be stored separately from acids, reducing agents, inflammables, combustibles, reducing agents, etc.
3. The lighting and ventilation facilities in the storage room are explosion-proof, with switches located outdoors.
4. When handling, care should be taken to prevent damage to packaging and containers, and impact and oscillation are prohibited. Personal protection should be taken during packaging and handling operations.
5. Please carefully read our factory's Safety Technical Manual (MSDS) when storing, transporting, and using this product.
Product validity period:
Store and transport in strict accordance with the manufacturer's instructions. The product quality can be guaranteed within six months.
Fire protection:
1.This product may decompose violently due to heating, and may ignite violently. A small amount of small fires should be put out quickly with foam or dry powder extinguishers.
2. The fire should be quickly evacuated to a safe distance and rescued with a water gun, and the fire department should be notified for handling.