LPO-過(guò)氧化二月桂酰--CAS.105-74-8
公司: | 山東海京新材料有限公司 |
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聯(lián)系人: | 劉總 |
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電話(huà): | 0536-8688945 |
地址: | 山東省濰坊市濱海區(qū)大家洼街道海化街鳶 都大廈1號(hào)樓601 |
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產(chǎn)品介紹
商品名稱(chēng):LPO
中文名稱(chēng):過(guò)氧化二月桂酰
化學(xué)名稱(chēng):過(guò)氧化二月桂酰
分子式:C24H46O4
分子量:398.6
理論活性氧含量:4.01%
CAS號(hào):105-74-8
Einecs:203-326-3
主要分解產(chǎn)物: CO2、月桂酸酯
指標(biāo):
半衰期:
0.1小時(shí):99℃
1小時(shí):79℃
10小時(shí):61℃
熱穩(wěn)定性數(shù)據(jù):
自加速分解溫度(SADT):50℃
危急溫度(Tem):45℃
控制溫度(Tc):--
貯存溫度(Tsmax):--/30 ℃
技術(shù)標(biāo)準(zhǔn):
外觀:白色粉狀或片狀固體
含量:≥99.0%
用途:本產(chǎn)品是乙烯、苯乙烯、氯乙烯、偏二氯乙烯、丙烯酸酯和甲基丙烯酸酯和聚合引發(fā)劑。
包裝:
LPO的標(biāo)準(zhǔn)包裝是凈重25公斤的紙板桶,或瓦楞紙箱內(nèi)裝四個(gè)5公斤塑料袋,凈重20公斤。也可按用戶(hù)的要求的規(guī)格包裝。
LPO為D類(lèi)固體有機(jī)過(guò)氧化物,貨物分類(lèi):5.2,聯(lián)合國(guó)編號(hào):3106,二類(lèi)危險(xiǎn)貨物包裝.
注意事項(xiàng):
(1) 遠(yuǎn)離火種、明火和熱源。
(2) 避免接觸還原劑(如胺類(lèi))、酸、堿和重金屬化合物(如促進(jìn)劑、金屬皂等)
(3) 請(qǐng)參照本產(chǎn)品的數(shù)據(jù)表(MSDS)。
用途:
1. 氯乙烯的聚合:
LPO廣泛地應(yīng)用于水相懸浮聚合和本體聚合反應(yīng)中,聚合的溫度范圍為60-75℃,很多情況下,LPO和其它高活性的過(guò)氧化物復(fù)配使用,例如,過(guò)氧化二碳酸酯類(lèi)(過(guò)氧化二碳酸雙-4-叔丁基環(huán)已烷),或過(guò)氧酯類(lèi)(過(guò)氧化新癸酸-1,1,3,3-四甲基丁酯),可以增加其反應(yīng)活性。
2. 乙烯的聚合:
LPO使用于高壓聚乙烯的聚合引發(fā),由于它的溶解性較差,在很多情況下被過(guò)氧化異壬酰所取代,但是LPO的優(yōu)點(diǎn)是它可在常溫下保存。
3. 丙烯酸酯和甲基丙烯酸酯的聚合:
LPO也可以用于丙烯酸酯的聚合反應(yīng),聚合反應(yīng)溫度為60-90℃。
4. ABS樹(shù)脂的聚合引發(fā)劑:
LPO同時(shí)也是ABS聚合反應(yīng)的重要引發(fā)劑,它和1,1-二叔丁基過(guò)氧化-3,3,5-三甲基環(huán)已烷(LQ-CH335)復(fù)配使用,具有很好的引發(fā)效果。
Product name:LPO
English name:Dilauroyl peroxide
Chemical name: lauroyl peroxide
Molecular formula:C24H46O4
Molecular weight:398.6
Theoretical active oxygen content:4.01%
CAS.:105-74-8
Einecs:203-326-3
Main decomposition products: CO2, laurate
Safety indicators:
Half life (measured in chlorobenzene solution):
0.1 hour: 99 ℃
1 hour: 79 ℃
10 hours: 61 ℃
Thermal stability data:
Self accelerating decomposition temperature (SADT): 50 ℃
Emergency temperature (Tem): 45 ℃
Control temperature (Tc):--
Storage temperature (Tsmax): --/30 ℃
Technical standards:
Appearance: White powder or flake solid
Content:≥99.0%
Usage: This product is ethylene, styrene, vinyl chloride, vinylidene chloride, acrylate, methacrylate, and polymerization initiator.
packing:
The standard packaging for LPO is a cardboard drum with a net weight of 25 kilograms, or a corrugated cardboard box containing four plastic bags with a net weight of 20 kilograms. It can also be packaged according to the specifications requested by the user.
LPO is a Class D solid organic peroxide, cargo classification: 5.2, UN number: 3106, packaging for Class II dangerous goods
Safety precautions:
(1) Keep away from sparks, open flames, and heat sources.
(2) Avoid contact with reducing agents (such as amines), acids, bases, and heavy metal compounds (such as accelerators, metal soaps, etc.)
(3) Please refer to the Safety Data Sheet (MSDS) of this product.
Purpose:
1. Polymerization of vinyl chloride:
LPO is widely used in aqueous suspension polymerization and bulk polymerization reactions, with polymerization temperatures ranging from 60 to 75 ℃. In many cases, LPO can be used in combination with other highly active peroxides, such as peroxydicarbonate esters (peroxydicarbonate di-4-tert-butyl cyclohexane) or peroxyesters (peroxyneodecanoic acid-1,1,3,3-tetramethylbutyl ester), which can increase their reaction activity.
2. Ethylene polymerization:
LPO is used for polymerization initiation of high-pressure polyethylene, and due to its poor solubility, it is often replaced by isononyl peroxide. However, the biggest advantage of LPO is that it can be stored at room temperature.
3. Polymerization of acrylate and methacrylate:
LPO can also be used for the polymerization reaction of acrylic esters, with a polymerization temperature of 60-90 ℃
4. Polymerization initiator for ABS resin:
LPO is also an important initiator for ABS polymerization reaction. It is used in combination with 1,1-ditert-butylperoxy-3,3,5-trimethylcyclohexane (LQ-CH335) and has a good initiating effect.