TBPO--叔丁基過氧-2-乙基己酸酯---CAS.3006-82-4
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產(chǎn)品介紹
商品名稱:TBPO (TBPEH)
英文名稱:過氧化-2-乙基已酸叔丁酯
化學名稱:過氧化-2-乙基已酸叔丁酯
分子式:C12H14O3
分子量:216.4
理論活性氧量:7.40%
CAS號:3006-82-4
UN No. 3113
級別l: 5.2
C液體有機過氧化物,控溫運輸。鐵路運輸和空運被禁止。
主要分解產(chǎn)物:叔丁醇、甲烷、2-乙基已酸、正庚烷、乙烷、CO2等。
指標:
半衰期 :
0.1小時:113℃
1小時:91℃
10小時:72℃
熱穩(wěn)定性數(shù)據(jù):
自加速分解溫度(SADT):35℃
危急溫度(Tem):25℃
控制溫度(Tc):20℃
貯存溫度(Tsmax):-30/20℃
活化能E(KJ/mol):124.9
技術標準:
外觀:透明液體
色度:20APHA
含量:97% min
TBHP:較大0.1%
無機及有機可水解氯化物:100mg/kg max
用途:
1.本產(chǎn)品是乙烯聚合常選用的聚合引發(fā)劑,適用于釜式和管式法工藝中。也是丙烯酸酯類和甲基丙烯酸酯類的聚合引發(fā)劑,適用溫度范圍80-150℃。
2. 本產(chǎn)品可以使用于苯乙烯的聚合引發(fā),其活性優(yōu)于BPO,也可以與TBPB和TBEC等過氧化物復配使用。也是醋酸乙烯(EVA)共聚物的重要引發(fā)劑。
3. 為不飽和聚酯的高溫固化劑,固化溫度為120-160℃,選擇UP于熱壓模塑法固化工藝(DMC、BMC),也可和鈷類促進劑作用,在60℃用于氣干漆和纏繞成型工藝。
包裝及運輸:
標準包裝為20公斤的聚乙烯包裝。也可根據(jù)客戶的要求的包裝尺寸供貨,客戶可在訂貨時提出要求。
儲存注意事項Storage precautions:
1.儲存于陰涼通風的空間內(nèi),倉溫不超過20℃。
2. 遠離火種,熱源。應與酸類,還原劑,易燃物,可燃物,還原劑等分開存放。
3. 儲存間的照明通風等設施采用防爆型,開關設在戶外。
4. 搬運時應小心輕放,防止包裝及容器的破損,禁止撞擊和振蕩,分裝和搬運作業(yè)要注意個人防護。
5. 請客戶在貯運和使用本產(chǎn)品時仔細閱讀《技術說明書(MSDS)》。
產(chǎn)品有效期:
在嚴格按照生產(chǎn)廠家提示的條件貯存、運輸。三個月內(nèi)產(chǎn)品質(zhì)量可確實保證。
火災防護:
1.本產(chǎn)品可能因受熱而劇烈分解,會猛烈起火,少量產(chǎn)品小火應迅速用泡沫或干粉滅火器進行滅火。
2. 大火應迅速撤達到不危險的距離以外并用水槍樸救,通知消防部門處理。
Product name:TBPO (TBPEH)
English name:Tert-Butyl peroxy-2-ethylhexanoate
Chemical name: tert butyl peroxy-2-ethylhexanoate
Molecular formula:C12H14O3
Molecular weight:216.4
Theoretical active oxygen content:7.40%
CAS.:3006-82-4
UN No. 3113
Level: 5.2
C-type liquid organic peroxide, temperature controlled transportation. Railway and air transportation are prohibited.
Main decomposition products: tert butanol, methane, 2-ethylhexanoic acid, n-heptane, ethane, CO2, etc.
Safety indicators:
Half life:
0.1 hour: 113 ℃
1 hour: 91 ℃
10 hours: 72 ℃
Thermal stability data:
Self accelerating decomposition temperature (SADT): 35 ℃
Emergency temperature (Tem): 25 ℃
Control temperature (Tc): 20 ℃
Storage temperature (Tsmax): -30/20 ℃
Activation energy E (KJ/mol): 124.9
Technical standards:
Appearance: Colorless transparent liquid
Chromaticity:20APHA
Content: 97% min
TBHP:0.1% max
Inorganic and organic hydrolyzable chlorides: 100mg/kg max
Purpose:
1. This product is a commonly used polymerization initiator for ethylene polymerization, suitable for both kettle and tube processes. It is also a polymerization initiator for acrylates and methacrylates, with a suitable temperature range of 80-150 ℃.
2. This product can be used for polymerization initiation of styrene, with better activity than BPO, and can also be used in combination with peroxides such as TBPB and TBEC. It is also an important initiator for ethylene acetate (EVA) copolymers.
3. It is a high-temperature curing agent for unsaturated polyester, with a curing temperature of 120-160 ℃. It is preferred for UP in the hot pressing molding process (DMC, BMC), and can also interact with cobalt type accelerators for air drying paint and winding molding processes at 60 ℃.
Packaging and transportation:
The standard packaging is 20 kilograms of polyethylene packaging. We can also supply according to the packaging size requested by the customer, and the customer can make requirements when placing an order.
Storage precautions:
1. Store in a cool and ventilated space, with a warehouse temperature not exceeding 20 ℃.
2. Keep away from sparks and heat sources. It should be stored separately from acids, reducing agents, inflammables, combustibles, reducing agents, etc.
3. The lighting and ventilation facilities in the storage room are explosion-proof, with switches located outdoors.
4. When handling, care should be taken to prevent damage to packaging and containers, and impact and oscillation are prohibited. Personal protection should be taken during packaging and handling operations.
5. Please carefully read the Safety Technical Manual (MSDS) when storing, transporting, and using this product.
Product validity period:
Store and transport in strict accordance with the manufacturer's instructions. The product quality can be guaranteed within three months.
Fire protection:
1. This product may decompose violently due to heating, and will ignite violently. A small amount of small fires should be put out quickly with foam or dry powder extinguishers.
2. The fire should be quickly evacuated to a safe distance and rescued with a water gun, and the fire department should be notified for handling.