TBPD-過(guò)氧化新癸酸叔丁酯--CAS.26748-41-4
公司: | 山東海京新材料有限公司 |
---|---|
聯(lián)系人: | 劉總 |
手機(jī): | 13220762561 |
電話: | 0536-8688945 |
地址: | 山東省濰坊市濱海區(qū)大家洼街道?;著S 都大廈1號(hào)樓601 |
留言咨詢 更多信息 | |
分享: |
![]() |
產(chǎn)品介紹
商品名稱:TBPD
中文名稱:過(guò)氧化新葵酸叔丁酯
化學(xué)名稱:過(guò)氧化新癸酸叔丁酯
分子式:C14H28O3
分子量:244.4
理論活性氧量:6.55%
CAS號(hào):26748-41-4
UN No. 3115
IMO/IMDG 5235a
級(jí)別:5.2
公路運(yùn)輸(ARD):5.2 15b
D型液體有機(jī)過(guò)氧化物,禁止鐵路運(yùn)輸和空運(yùn)。
性質(zhì):
本品為透明液體,用已烷、無(wú)嗅礦物油、異十二烷等配制稀釋?;蚩捎每蛻糁付ǖ娜軇┫♂?。不溶于水,溶于多數(shù)有機(jī)溶劑,比重(20℃) 0.880。
主要分解產(chǎn)物:叔丁醇、新癸酸、甲烷等
指標(biāo):
半衰期 :
0.1小時(shí):83℃
1小時(shí):64℃
10小時(shí):46℃
熱穩(wěn)定性數(shù)據(jù):
自加速分解溫度(SADT):15℃
危急溫度(Tem):5℃
控制溫度(Tc):-5℃
貯存溫度 (Tsmax/TSmin):-10/-30 ℃
活化能 E (KJ/mol):115.47
技術(shù)標(biāo)準(zhǔn):
外觀:透明液體
含量 :75% min
有效氧:4.91% min
游離酸:0.15% max
TBHP:0.1% max
用途:
1.高壓聚乙烯(LDPE)的優(yōu)良低溫引發(fā)劑,多用于管式法工藝, 可同引發(fā)劑TBPV(過(guò)氧化特戊酸叔丁酯),TBPEH(過(guò)氧化-2-乙基已酸叔丁酯),引發(fā)劑TBPB(過(guò)氧化苯甲酸叔丁酯)等共同組成復(fù)合引發(fā)劑體系,聚合效果好。
2. 是不飽和聚酯的高溫固化劑。
3. 可用于氯乙烯,苯乙烯或苯乙烯的共聚物聚合引發(fā)劑及甲基丙烯酸酯、醋酸乙烯酯的聚合引發(fā)劑。
包裝及運(yùn)輸:
標(biāo)準(zhǔn)包裝為20公斤的聚乙烯包裝。也可根據(jù)客戶要求的包裝尺寸供貨,客戶可在訂貨時(shí)提出要求。
儲(chǔ)存注意事項(xiàng):
1.儲(chǔ)存于陰涼通風(fēng)的空間內(nèi),倉(cāng)溫不超過(guò)-10℃。
2. 遠(yuǎn)離火種,熱源。應(yīng)與酸類,易燃物,可燃物,還原劑等分開存放。
3. 儲(chǔ)存間的照明通風(fēng)等設(shè)施采用防爆型,開關(guān)設(shè)在戶外。
4. 搬運(yùn)時(shí)應(yīng)小心輕放,防止包裝及容器的破損,禁止撞擊和振蕩,分裝和搬運(yùn)作業(yè)要注意個(gè)人防護(hù)。
5. 請(qǐng)客戶在貯運(yùn)和使用本產(chǎn)品時(shí)仔細(xì)閱讀《技術(shù)說(shuō)明書(MSDS) 》。
產(chǎn)品有效期:
在嚴(yán)格按照生產(chǎn)廠家提示的條件貯存、運(yùn)輸?shù)那闆r下,三個(gè)月內(nèi)產(chǎn)品質(zhì)量可確實(shí)保證。
火災(zāi)防護(hù):
1、本產(chǎn)品可能因受熱而劇烈分解,會(huì)猛烈起火,少量產(chǎn)品小火應(yīng)迅速用泡沫或干粉滅火器進(jìn)行滅火。
2、大火應(yīng)迅速撤離到不危險(xiǎn)的距離以外并用水槍撲救,通知消防部門處理。
Product name:TBPD
English name:Tert-butyl peroxyneodecanoate
Chemical name: tert butyl peroxyneodecanoate
Molecular formula:C14H28O3
Molecular weight:244.4
Theoretical active oxygen content:6.55%
CAS.:26748-41-4
UN No. 3115
IMO/IMDG 5235a
Level:5.2
ARD:5.2 15b
D-type liquid organic peroxide, prohibited for railway and air transportation.
Property:
This product is a colorless transparent liquid, diluted with hexane, odorless mineral oil, isododecane, etc. Alternatively, the solvent specified by the customer can be used for dilution. Insoluble in water, soluble in most organic solvents, with a specific gravity of 0.880 at 20 ℃.
Main decomposition products: tert butanol, neodecanoic acid, methane, etc
Safety indicators:
Half life:
0.1小時(shí):83℃ 0.1 hour: 83 ℃
1小時(shí):64℃ 1 hour: 64 ℃
10小時(shí):46℃ 10 hours: 46 ℃
Thermal stability data:
SADT:15℃
Self accelerating decomposition temperature (SADT): 15 ℃
Emergency temperature (Tem): 5 ℃
Control temperature (Tc): -5 ℃
Storage temperature (Tsmax/TSmin):-10/-30 ℃
Activation energy E (KJ/mol):115.47
Technical standards:
Appearance: Colorless transparent liquid
Content: 75% min
Effective oxygen: 4.91% min
Free acid: 0.15% max
TBHP:0.1% max
Purpose:
1. High pressure polyethylene (LDPE) is an excellent low-temperature initiator, commonly used in tubular processes. It can be combined with initiators TBPV (tert butyl peroxyvalerate), TBPEH (tert butyl peroxy-2-ethylhexoate), and TBPB (tert butyl peroxybenzoate) to form a composite initiator system, resulting in better polymerization effects.
2. It is a high-temperature curing agent for unsaturated polyester.
3. It can be used as a copolymer polymerization initiator for vinyl chloride, styrene or styrene, as well as a polymerization initiator for methacrylate and vinyl acetate.
Packaging and transportation:
The standard packaging is 20 kilograms of polyethylene packaging. We can also supply according to the packaging size requested by the customer, and the customer can make a request when placing an order.
Storage precautions:
1. Store in a cool and ventilated space, with a warehouse temperature not exceeding -10 ℃.
2. Keep away from sparks and heat sources. It should be stored separately from acids, combustibles, combustibles, reducing agents, etc.
3. The lighting and ventilation facilities in the storage room are explosion-proof, with switches located outdoors.
4. When handling, care should be taken to prevent damage to packaging and containers, and impact and oscillation are prohibited. Personal protection should be taken during packaging and handling operations.
5. Please carefully read the Safety Technical Manual (MSDS) when storing, transporting, and using this product.
Product validity period:
Under strict storage and transportation conditions according to the manufacturer's instructions, product quality can be guaranteed within three months.
Fire protection:
1. This product may decompose violently due to heating, and may ignite violently. A small amount of small fires should be put out quickly with foam or dry powder extinguishers.
2. The fire should be quickly evacuated to a safe distance and extinguished with a water gun, and the fire department should be notified for handling.